Atomic Layer Deposition of Gallium Oxide Films as Gate Dielectrics in AlGaN/GaN Metal-Oxide-Semiconductor High-Electron-Mobility Transistors

Abstract

In this study, films of gallium oxide (Ga^sub 2^O3) were prepared through remote plasma atomic layer deposition (RP-ALD) using triethylgallium and oxygen plasma. The chemical composition and optical properties of the Ga^sub 2^O3 thin films were investigated; the saturation growth displayed a linear dependence with respect to the number of ALD cycles. These uniform ALD films exhibited excellent uniformity and smooth Ga^sub 2^O3-GaN interfaces. An ALD Ga^sub 2^O3 film was then used as the gate dielectric and surface passivation layer in a metal-oxide-semiconductor high-electron-mobility transistor (MOS-HEMT), which exhibited device performance superior to that of a corresponding conventional Schottky gate HEMT. Under similar bias conditions, the gate leakage currents of the MOS-HEMT were two orders of magnitude lower than those of the conventional HEMT, with the power-added efficiency enhanced by up to 9 %. The subthreshold swing and effective interfacial state density of the MOS-HEMT were 78 mV decade^sup -1^ and 3.62×10^sup 11^ eV^sup -1^ cm^sup -2^, respectively. The direct-current and radio-frequency performances of the MOS-HEMT device were greater than those of the conventional HEMT. In addition, the flicker noise of the MOS-HEMT was lower than that of the conventional HEMT.

Shih et al. Nanoscale Research Letters (2016) 11:235 DOI 10.1186/s11671-016-1448-z

NANO EXPRESS Open Access

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Web End = Atomic Layer Deposition of Gallium Oxide Films as Gate Dielectrics in AlGaN/GaN MetalOxideSemiconductor High-Electron-Mobility Transistors

Huan-Yu Shih1, Fu-Chuan Chu2, Atanu Das2, Chia-Yu Lee2, Ming-Jang Chen1 and Ray-Ming Lin2*

Abstract

In this study, films of gallium oxide (Ga2O3) were prepared through remote plasma atomic layer deposition (RP-ALD) using triethylgallium and oxygen plasma. The chemical composition and optical properties of the Ga2O3 thin

films were investigated; the saturation growth displayed a linear dependence with respect to the number of ALD cycles. These uniform ALD films exhibited excellent uniformity and smooth Ga2O3GaN interfaces. An

ALD Ga2O3 film was then used as the gate dielectric and surface passivation layer in a metaloxidesemiconductor high-electron-mobility transistor (MOS-HEMT), which exhibited device performance superior to that of a corresponding conventional Schottky gate HEMT. Under similar bias conditions, the gate leakage currents of the MOS-HEMT were two orders of magnitude lower than those of the conventional HEMT, with the power-added efficiency enhanced by up to 9 %. The subthreshold swing and effective interfacial state density of the MOS-HEMT were78 mV decade1 and 3.62 1011 eV1 cm2, respectively. The direct-current and radio-frequency performances of the MOS-HEMT device were greater than those of the conventional HEMT. In addition, the flicker noise of the MOS-HEMT was lower than that of the conventional HEMT.

Keywords: GaN, Ga2O3, Remote plasma atomic layer deposition (RP-ALD), Metaloxidesemiconductor high-electron-mobility transistor (MOS-HEMT), MOCVD

Background

Gallium nitride (GaN)-based semiconductor materials are useful not only in optoelectronic devices but also in millimeter-wave power devices, especially for the fabrication of high-electron-mobility transistors (HEMTs) [1, 2]. For microwave power applications, an AlGaN/GaN HEMT must exhibit high speed, high radio-frequency (RF) power performance, and a high breakdown voltage [3]. Nevertheless, a high gate leakage current is the factor most responsible for limiting the direct-current (DC) and RF power performances of conventional Schottky gate HEMTs [4]. Metaloxide semiconductor HEMTs (MOS-HEMTs) can decrease the gate leakage current when incorporating a variety

of gate oxide/insulators, including electron beam (EB)-evaporated Pr2O3 and Er2O3 [5, 6], thermally oxidized

TiO2/NiO [7], sputtered Al2O3 [8], and atomic layer-deposited HfO2 and Al2O3 [9, 10].

Among the established dielectric deposition methods, atomic layer deposition (ALD)a low-temperature chemical vapor deposition technique in which layer-by-layer deposition occurs based on surface-limited reactionsis attractive because of its accurate control over thickness, excellent step coverage, conformity, high uniformity over large areas, low-defect density, good reproducibility, and low deposition temperatures arising from the self-limiting reactions [11]. These features make ALD a strong candidate for manufacturing nanoscale dielectric layers for electronic devices. Indeed, ALD has been exploited to prepare a variety of high-dielectric-constant (high-k) materials (e.g., Al2O3 [12], HfO2 [13],

ZrO2 [14]) that are used widely in Si-based devices.

* Correspondence: mailto:[email protected]

Web End [email protected]

2Department of Electronic Engineering, Chang Gung University, Taoyuan 333, TaiwanFull list of author information is available at the end of the article

2016 Shih et al. Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/

Web End =http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

Shih et al. Nanoscale Research Letters (2016) 11:235 Page 2 of 9

ALD-deposited high-k materials, including HfO2, Sc2O3, and Al2O3, have been employed as gate dielectric and surface passivation layers to improve the properties of HEMTs [15]. In addition, such binary oxides are thermodynamically stable when they are contacted with IIIV semiconductors. Among the high-k materials, trivalent Ga2O3 is a promising material for application as a gate dielectric and passivation layer in IIIV semiconductor-based devices because its large band gap (4.9 eV) and moderate dielectric constant (10.6) can help to decrease the leakage current [16]. It was also reported that Ga2O3 could be a good candidate as a gate dielectric of AlGaN/GaN HEMTs due to the good interface characteristics [17].

Several groups have reported the ALD growth of Ga2O3. Shan et al. performed thermal ALD of GaN using [(CH3)2GaNH2]3 and O2 plasma as precursors[18]. In 2012, Comstock and Elam described the ALD of Ga2O3 films from trimethylgallium and ozone [19]. In 2013, Donmez et al. applied low-temperature ALD to grow Ga2O3 thin films from trimethylgallium and O2 plasma [20]. A temperature window of 100400 C has been reported for this process.

In this present study, we prepared high-quality Ga2O3 thin films through remote plasma atomic layer deposition (RP-ALD) using triethylgallium (TEG) and O2 plasma. The remote plasma configuration avoided plasma-induced damage because the wafer was not exposed directly to the plasma, and low-temperature growth mode could realize selective growth by the lift-off method, it made the process much easier and convenient. After investigating the ALD window and characteristics of the Ga2O3 films, we examined their deposition on AlGaN

Schottky layers. Comparing the DC and RF characteristics with those of conventional systems, our proposed ALD Ga2O3 dielectrics on AlGaN/GaN HEMTs appear to be very promising devices.

Methods

Ga2O3 was prepared through remote plasma ALD (Fiji F202, Cambridge Nanotech) using TEG and O2 plasma as precursors. The remote O2 plasma was generated by an RF coil under an alternative RF power at 300 W. Figure 1 provides a schematic representation of the ALD cycles during the Ga2O3 deposition process. Each ALD cycle comprised four steps: (1) TEG pulse, (2) Ar purge,(3) O2 plasma, and (4) Ar purge. The films were deposited at a temperature of 250 C with a base pressure of approximately 0.4 Torr.

The thickness and optical characteristics of the Ga2O3

thin films were measured through spectroscopic ellipsometry (SE, Elli-SE, Ellipso Technology) in the wavelength range 280980 nm at an incident angle of 70. The film thickness was confirmed using high-resolution transmission electron microscopy (HRTEM). The chemical compositions and bonding states in the films were characterized using X-ray photoelectron spectrometry (XPS) with Al K (1486.6 eV) radiation; pre-sputtering was performed for 10 s to remove any contamination from the surface. The crystal structure of the Ga2O3 films were characterized by high-power grazing incidence the X-ray diffractometer (GI-XRD; Rigaku TTRAX 3, 18 kW) in 2 mode with Cu K radiation. Atomic force microscopy (AFM; Bruker, Edge) was used to evaluate the roughness of the Ga2O3 surface and interface.

The epitaxial structure was grown on a 2-in silicon carbide substrate using a Nippon Sanso SR-2000 metal-organic chemical vapor deposition system (MOCVD). The epilayer consisted of a 26-nm Al0.275Ga0.725N barrier

layer, a 1-nm AlN inter layer, a 2-m GaN layer, a 0.7-m Al0.07Ga0.93N transition layer, and a 300-nm AlN buffer layer. All epitaxial layers were unintentionally doped. The HEMT structure exhibited a sheet charge density of 1.02 1013 cm2 and a Hall electron mobility

of 1880 cm2 V1 s1 at 300 K.

Fig. 1 Schematic representation of the ALD process during Ga2O3 deposition

Shih et al. Nanoscale Research Letters (2016) 11:235 Page 3 of 9

Fig. 2 a Schematic representation of the cross-sectional structure of a Ga2O3/AlGaN/AlN/GaN HEMT. b Cross-sectional TEM image of a

GaN/AlN/AlGaN/Ga2O3/Ni/Au structure

Devices were processed using conventional optical lithography and lift-off technology. Device isolation was accomplished through mesa dry etching down to the unintentionally doped GaN layer in a BCl3 plasma reactive ion etching chamber. Ohmic contacts of Ti/Al/Ni/Au (19/120/30/75 nm) metals were deposited through EB evaporation, followed by rapid thermal annealing at 850 C for 30 s in a N2-rich chamber. After gate lithography pattern formation and surface cleaning, the samples were loaded into the ALD chamber, and a 10-nm Ga2O3 layer was deposited at 250 C to function as the gate dielectric and passivation layer between the source and drain contact. Ni/Au (70/140 nm) gate metals were then deposited. For comparison, a conventional Ni/Au

Schottky gate AlGaN/GaN HEMT was also fabricated. The Ti/Au (50/1100 nm) metals were deposited as interconnection and probe pads. A schematic cross-sectional structure and a cross-sectional TEM image of a Ga2O3/

AlGaN/AlN/GaN HEMT are presented in Fig. 2a, b, respectively. The gate dimensions of each device were 1 100 m2 with a source-to-drain spacing of 6 m. The microstructures of the fabricated devices were characterized using high-resolution transmission electron microscopy (HRTEM, FEI TecnaiG2 F20). DC characterization of the HEMT devices was performed using an Agilent B1500A semiconductor device analyzer; microwave power measurements were conducted using an ATN load-pull system.

Fig. 3 a Growth rate of the Ga2O3 thin films plotted with respect to the TEG pulse time and plasma time. b Film thickness plotted with respect to the number of applied ALD cycles

Shih et al. Nanoscale Research Letters (2016) 11:235 Page 4 of 9

Fig. 4 a Ga 3d and b O 1 s XPS spectra of the Ga2O3 thin film

Results and Discussion

Characteristics of ALD Ga2O3

Figure 3a displays the growth rate of the Ga2O3 thin

films as a function of the TEG pulse time and plasma time, at a deposition temperature of 250 C. The O2 flow rate was fixed at 20 sccm. The growth rate is defined here in terms of the film thickness divided by the total number of applied ALD cycles. We observed that the growth rate increased initially upon increasing the TEG dose, but then remained constant at 0.062 nm/cycle when the TEG pulse time was greater than 0.1 s. The growth rate became saturated at plasma times of longer than 5 s. These results suggest that the Ga2O3 thin films were grown in a self-limiting manner when using the RP-ALD technique. Figure 3b presents the film thickness plotted with respect to the number of applied ALD

cycles; the linear dependence implies that the deposition followed the ALD mode and that the film thickness could be control precisely by varying the number of ALD cycles.

Figure 4 displays the XPS spectra of a Ga2O3 thin film. A single binding energy (BE) peak for the Ga 3d core level, situated at 20.1 eV, confirmed the presence of GaO bonds [21] in the sample and the absence of elemental Ga in the film. A single, sharp O 1 s peak, centered at a BE of 531.0 eV, is consistent with previously reported values for the oxide [21]. Taken together, these features confirm that the RP-ALD system facilitated the successful deposition of Ga2O3 thin films. By measuring relative areas under the curves of the XPS spectra, we calculated average atomic compositions for Ga, O, and C of 41.53,58.26, and 0.21 %, respectively, in the Ga2O3 thin film.

Fig. 5 Refractive index and extinction coefficient of the Ga2O3 thin

film plotted with respect to the wavelength

Fig. 6 The GI-XRD pattern of the Ga2O3 films

Shih et al. Nanoscale Research Letters (2016) 11:235 Page 5 of 9

Fig. 7 Atomic force microscopy images of the conventional HEMT and the Ga2O3 MOS-HEMT

The molecular ratio of Ga and O in the ALD thin film was slightly higher than ideal (2:3), suggesting the existence of a Ga-rich Ga2O3 film featuring some O vacancies. The content of carbon atoms was negligible, suggesting that the ethyl groups of TEG had been removed almost completely during exposure to the remote O2 plasma.

We used SE to investigate the optical properties of the Ga2O3 thin film. Figure 5 displays the dispersion of the refractive index and extinction coefficient at wavelengths in the range 280980 nm. We fitted the SE data to the TaucLorentz model, which is widely used for amorphous semiconductors [22]. The measured refractive index of our ALD Ga2O3 at a wavelength of 633 nm was 1.91, and its band gap was 4.51 eV; these values are close to those reported [23] for amorphous Ga2O3. Figure 6 shows the GI-XRD pattern of the Ga2O3 films. The result was performed with a low-grazing angle of incidence in order to obtain the signal from the thin film. There are no obvious peaks of Ga2O3 so that the crystal structure was amorphous which was consistent with the SE results.

To investigate the interface quality, the roughness of the HEMT structure before and after Ga2O3 grown by

ALD were measured by atomic force microscopy (AFM), as shown in Fig. 7. The roughness remained the same order after deposition, this result indicated that the interface between AlGaN and Ga2O3 should be smooth.

Characteristics of Ga2O3 MOS-HEMT

The capacitance-voltage (C-V) characteristic measured at 1 MHz is shown Fig. 8. The Cox value come from

MOS capacitance; the calculated Cox values of the conventional HEMT and the Ga2O3 MOS-HEMT were 28 pF and 14.7 pF, respectively.

Figure 9 displays the measured IDSVDS characteristics of the conventional HEMT and the Ga2O3 MOS

HEMT; they both exhibited good gate modulation and pinch-off characteristics. The measured drain current of the conventional HEMT at a value of VG of 0 V (IDSS) was 609 mA mm1; it was slightly

higher (720 mA mm1) for the Ga2O3 MOS-HEMT. Figure 10a presents the transconductance (gm) and

drain current (IDS) characteristics for these devices. The maximum transconductances (gm max) of the conventional HEMT and Ga2O3 MOS-HEMT when biased at a value of VDS of 8 V were 179 and 200 mS mm1, respectively; their maximum drain currents (IDS max) were

921 and 1123 mA mm1, respectively. Thus, the values of IDS max and gm max of the MOS-HEMT were relatively

high, presumably the result of enhanced mobility caused by decreased carrier scattering, due to surface passivation [24, 25]. In addition, the slight increase in the gate-to-channel separation, resulting from the presence

Fig. 8 The capacitance-voltage (C-V) characteristics of the conventional HEMT and the Ga2O3 MOS-HEMT

Shih et al. Nanoscale Research Letters (2016) 11:235 Page 6 of 9

SS ln10

qKT 1

Cox

Fig. 9 IDSVDS characteristics of the conventional HEMT and the Ga2O3 MOS-HEMT upon varying the value of VG from 6 to +2 V at a step of +1 V

of the Ga2O3 gate oxide layer, was responsible for the threshold voltage shifting from 3.8 to 4.2 V. For the HEMT with Ga2O3, the threshold voltage (Vth)

shift, which was generally resulted from the defects in interface and gate oxide, was smaller than that with Al2O3 [26] and HfO2 [27]. The result may be caused by the excellent interface between Ga2O3 and AlGaN, optimized RP-ALD process condition, and the use of TEG (reduce defects in Ga2O3). To further investigate the gate control characteristics of both devices, we studied the region near the cut-off voltage. The subthreshold swing (SS) is a parameter that indicates how effectively a device can be turned off; it is defined as the decrease in the log (IDS)VGS plot near the cut-off voltage as shown in Fig. 10b. We measured the values of IDS with

respect to VGS for both devices biased at a value of VDS of 8 V. The ION/IOFF ratio and SS of the Ga2O3 MOSHEMT (1.5 107 and 78 mV decade1, respectively) were superior to those of the conventional HEMT(2.4 105 and 188 mV decade1, respectively). Figure 10b

also displays the values of the OFF-state IDS, revealing that the leakage current (3.3 103 mA mm1) of the conventional HEMT decreased (to 7.45 105 mA

mm1) after deposition of the Ga2O3 thin layer. We calculated the effective interfacial state density from the SS [6]. By neglecting the depletion capacitance in the active layer, the value of Nt can be estimated as

Nt

q ; 1

where K is the Boltzmann constant, T is the temperature, Cox is the capacitance of the gate oxide and q is the quantity of one electron, respectively. The effective interfacial states density (4.77 1012 eV1 cm2) of

the conventional HEMT decreased to 3.62 1011 eV1

cm2 for the Ga2O3 MOS-HEMT.

Figure 11a presents the gate leakage current densities of the two devices. Under reverse bias conditions, the leakage current density of the Ga2O3 MOS-HEMT reached as low as 7.8 106 mA mm1 at a value of VGD of 10 V; this leakage current density is two order of magnitude lower than that of the conventional HEMT (8.59 104 mA mm1). Figure 11b displays the three-terminal off-state breakdown characteristics of the conventional HEMT and Ga2O3 MOS-HEMT measured at a value of VGS of 6 V. The drain breakdown

voltage of the Ga2O3 MOS-HEMT (170 V) was 44 V larger than that of the conventional HEMT fabricated on the same wafer. The high quality of the ALD Ga2O3

film effectively suppressed the gate leakage current density and improved the breakdown voltage because of its large band gap [16].

We conducted 1/f noise measurements to elucidate the relationship between the low-frequency noise and the gate electrode interface; here, we varied the frequency from 1 to 100 KHz and the gate overdrive bias

Fig. 10 a Transfer characteristics and b log IDS vs VGS plots of the conventional HEMT and the Ga2O3 MOS-HEMT

Shih et al. Nanoscale Research Letters (2016) 11:235 Page 7 of 9

Fig. 11 a Gate leakage current and b three-terminal off-state breakdown characteristics of the conventional HEMT and the Ga2O3 MOS-HEMT

Fig. 12 a Normalized values of SID/ID2 plotted at various values of (VGSVth); b Hooges coefficient (H) plotted with respect to (VGSVth) for the conventional HEMT and the Ga2O3 MOS-HEMT

Shih et al. Nanoscale Research Letters (2016) 11:235 Page 8 of 9

(VGSVth) from 0.4 to 1 V in steps of 0.2 V. Figure 12a displays the gate bias dependence of the normalized drain current noise spectral density (SID/ID2) of both de

vices at a value of VDS of 2 V. The 1/f noise spectrum

of the Ga2O3 MOS-HEMT was lower than that of the conventional HEMT, due to its lower gate leakage current.

Our findings indicate that lower interfacial states can be achieved when using this ALD-deposited Ga2O3 film as a gate dielectric and passivation layer.

Furthermore, Hooges coefficient (H) is another noise parameter that quantifies the 1/f noise; it can provide a measure of the total number of active traps causing the noise and can be used as a rough figure of merit for both devices. Hooges coefficient can be expressed as follows [28]:

H

f WLCi VGSV th

SID qI2D

PoutPin

PAE

; 2

where f is the measurement frequency, Ci is the unit capacitance of the gate material, and q is the elementary electron charge.

Figure 12b presents the values of H plotted with respect to (VGSVth), measured at a value of f of 100 Hz.

The average values of H for the conventional HEMT and Ga2O3 MOS-HEMT were 1.4 102 and 1 103, respectively. The flicker noise spectral density of the Ga2O3

MOS-HEMT was lower than that of the conventional HEMT because of its lower number of interfacial states.

Figure 13 displays the microwave output power (Pout),

power gain (Gp), and power-added efficiency (PAE) characteristics for both devices determined at 2.4 GHz with a drain bias of 16 V, measured on-wafer by the load-pull ATN system with automatic tuners measuring the optimum-load impedance for maximum output

power. The conventional HEMT exhibited an output power of 25.6 dBm; the associated power-added efficiency was 40 % and the power gain was 21.9 dB. For the Ga2O3 MOS-HEMT, the output power was 27.3 dBm; the associated power-added efficiency was 49 % and the power gain was 23.6 dB. Output power and PAE can be expressed as

Pout

18 VDSV Kness

IDS 3

and

PDC 100%; 4

where Vknee is the knee voltage, Pout is the output power, Pin is the input power, and PDC is the DC power supply. The relatively high RF power performance of the Ga2O3

MOS-HEMT resulted from its higher current drive, lower PDC dissipation, and lower gate leakage current, all arising from the good passivation and gate insulation effects of the Ga2O3 film prepared through remote plasma ALD [5, 25, 29].

Conclusions

We have used remote plasma ALD to deposit Ga2O3 films that we then applied in AlGaN/AlN/GaN HEMTs on silicon carbide substrates. The thin Ga2O3 films prepared through RP-ALD exhibited saturation of the growth rate upon increasing the TEG pulse time and plasma time. The film thickness varied linearly with respect to the number of ALD cycles. This behavior is consistent with the growth of Ga2O3 following the ALD mode. The ALD Ga2O3 films possessed excellent uniformity and the Ga2O3GaN inter

faces were smooth. The fabricated Ga2O3 MOS-HEMT exhibited enhanced gate insulating and surface passivation effects, resulting in superior DC and RF performance relative to those of the conventional HEMT. Moreover, the low leakage current and low interfacial state density of the Ga2O3 MOS-HEMT provided a measured SS of 78 mV decade1 and an ION/IOFF ratio that was greater than 107 times that of the conventional HEMT. These attractive features of the HEMT incorporating the ALD-prepared Ga2O3 gate dielectric suggest that ALD-prepared Ga2O3 might find further applicability in other high-power devices in the near future.

Competing interestsThe authors declare that they have no competing interests.

Authors contributionsMJC conceived the idea and project. MJC and RML designed the experiments. HYS optimized the growth of the ALD GaN compliant buffer layer. FCC and CYL optimized the MOCVD epitaxy. CYL achieved the fabrication of HEMT devices. HYS and AD carried out the material analyses and devices electrical measurements. MJC provided the RP-ALD, and RML provided the MOCVD. HYS wrote the paper. All authors commented on the manuscript.

Fig. 13 Microwave power characteristics of the conventional HEMT and the Ga2O3 MOS-HEMT

Shih et al. Nanoscale Research Letters (2016) 11:235 Page 9 of 9

AcknowledgementsWe thank Nano Device Labs (NDL), Hsinchu, Taiwan, for the low-frequency noise and load-pull measurements. This study was supported financially by the National Science Council (NSC), Taiwan, under contract no. NSC-102-2221-E-182-060 and Chang Gung Memorial Hospital BMRP 591.

Author details

1Department of Material Science and Engineering, National Taiwan University, Taipei 10617, Taiwan. 2Department of Electronic Engineering, Chang Gung University, Taoyuan 333, Taiwan.

Received: 29 January 2016 Accepted: 20 April 2016

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